In recent research, biochar has been proven to reduce the greenhouse gases and promote organic matter during the composting. However, gas degradation may be related to the microstructure of compost. To investigate the mechanism of biochar additive, composting was performed using swine manure, wheat straw and biochar and representative solid compost samples were analyzed to characterize the mixed biochar and compost particles. We focused on the microscale, such as the particle size distributions, surface morphologies, aerobic layer thicknesses and the functional groups. The biochar and compost particle agglomerations gradually became weaker and the predominant particle size in the experiment group was < 200 mu m. The aerobic layer thickness (Lp) was determined by infrared spectroscopy using the wavenumbers 2856 and 1568 cm-1, which was 0-50 mu m increased as composting proceeded in both groups. The biochar increased Lp and facilitated oxygen penetrating the compost particle cores. Besides, in the biochar-swine manure particle interface, the aliphatic compound in the organic components degraded and the content of aromaticity increased with the composting process, which was indicated by the absorption intensity at 2856 cm-1 decreasing trend and the absorption intensity at 1568 cm-1 increasing trend. In summary, biochar performed well in the microscale of compost pile.
