Science of The Total Environment
+ 44 Science of The Total Environment
April 12, 2024
Differential influences of forest floor-pyrolyzed biochar-derived and leached dissolved organic matter interaction with natural iron-bearing minerals in forest subsoil on the formation of mineral-associated soil organic matter
The vertical sequestration of dissolved organic matter (DOM) by iron minerals along the soil profile is assumed to be central to the long-term storage of the soil organic matter (SOM) pool. However, there is limited information available about how the interaction between DOM and natural iron-bearing minerals shape mineral SOM as-sociations quantitatively and qualitatively in […]
April 12, 2024
Superior reduction and immobilization of Cr(VI) in soil utilizing sulfide nanoscale zero-valent iron supported by phosphoric acid-modified biochar: Efficiency and mechanism investigation
A novel strategy was proposed to remediate Cr(VI)-contaminated soil via phosphoric acid-modified biochar supported sulfide nanoscale zero-valent iron (SnZVI@PBC). Results of characterizations revealed that FeSX shell existed in outer layer of nZVI to prevent its oxidation after sulfidation modification, and SnZVI was effectively dispersed owing to the support of PBC, accelerating the electron transport for […]
April 12, 2024
Insights into the influence and mechanism of biomass substrate and thermal conversion conditions on Fe-N doped biochar as a persulfate activator for sulfamethoxazole removal
Fe-N-doped biochar is a promising material for advanced-oxidation heterogeneous catalysis, but its adsorption-catalytic performance is significantly affected by biomass feedstock compositions and thermal conversion conditions and is not yet conclusive. In this paper, four lignocellulosic biomasses (rice straw, bamboo, poplar wood, and corn stover) were selected as raw materials to prepare Fe-N-biochar as persulfate activators […]
April 12, 2024
Corn straw biochar addition elevated phosphorus availability in a coastal salt-affected soil under the conditions of different halophyte litter input and moisture contents
Improving salt-affected soil health using different strategies is of great significance for Sustainable Development Goals. The effects of biochar as a sustainable carbon negative soil amendment on phosphorous (P) pools in the degraded salt-affected soils of the of coastal wetlands (as one of the primary blue carbon ecosystems) with halophyte litter input under different water […]
April 12, 2024
Nitrogen (N) supplementation, slow release, and retention strategy improves N use efficiency via the synergistic effect of biochar, nitrogen-fixing bacteria, and dicyandiamide
Irrational nitrogen (N) fertilizer management and application practices have led to a range of ecological and environmental problems that seriously threaten food security. In this study, an effective N fertilizer management strategy was established for improving N fertilizer utilization efficiency (NUE). Biochar, N2-fixing bacteria (Enterobacter cloacae), and a nitrification inhibitor (dicyandiamide, DCD) were simultaneously added […]
April 12, 2024
Pyrolytic and hydrothermal carbonization affect the transformation of phosphorus fractions in the biochar and hydrochar derived from organic materials: A meta-analysis study
Carbonized organic materials are widely used to achieve soil improvement and alleviate soil pollution. The carbonization process significantly changes the total phosphorus (P) content and the P form in the solid phase derived from organic materials, which in turn has a significant impact on the P fertilizer effect in soils. In the present study, a […]
April 12, 2024
Effects of fir-wood biochar on CH4 oxidation rates and methanotrophs in landfill cover soils packed at three different proctor compaction levels
Application of biochar to landfill cover soils can purportedly improve methane (CH4) oxidation rates, but understanding the combined effects of soil texture, compaction, and biochar on the activity and composition of the methanotrophs is limited. The amendment of wood biochar on two differently textured landfill cover soils at three compaction levels of the Proctor density […]
April 12, 2024
Competitive adsorption behaviors and mechanisms of Cd, Ni, and Cu by biochar when coexisting with microplastics under single, binary, and ternary systems
In this study, the effects of coexistence with microplastics and co-ageing with the soil on adsorption behaviors and mechanisms of biochar for heavy metals were investigated. Adsorption experiments of Cd, Ni, and Cu by microplastics, biochar, and their combination were conducted in single, binary, and ternary systems. The results indicated that the heavy metal adsorption […]
April 12, 2024
Enhancing efficient reclaim of phosphorus from simulated urine by magnesium-functionalized biochar: Adsorption behaviors, molecular-level mechanistic explanations and its potential application
Magnesium-functionalized Magnolia grandiflora Linn leaf-derived biochar (MBC) capable of efficiently reclaiming phosphorus from urine was synthesized by slow co-pyrolysis. Four adsorption kinetic and seven adsorption isotherm models were fitted to the batch adsorption and desorption experimental data, and it was found that pseudo-first-order kinetic model and multilayer model with saturation best described the phosphate-phosphorus (PO43–P) […]
April 12, 2024
Using Fe/H2O2-modified biochar to realize field-scale Sb/As stabilization and soil structure improvement in an Sb smelting site
Antimony (Sb) and arsenic (As) released from the Sb smelting activities pose a major environmental risk and ecological degradation in Sb smelting sites. Here the effects of Fe/H2O2 modified biochar (Fe@H2O2-BC) on the synchronous stabilization of Sb/As and the improvement of soil structure in a typical Sb smelting site in Southern China based on a […]